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You asked:

is witch hazel the same thing as rubbing alcohol

No. Witch hazel is not the same as rubbing alcohol.
witch hazel

Witch hazel, the astringent produced from the leaves and bark of the North American Witch-hazel shrub, which grows naturally from Nova Scotia west to Ontario, Canada, and south to Florida and Texas in the United States

rubbing alcohol
rubbing alcohol
rubbing alcohol

rubbing alcohol (a liquid, used primarily for topical application, containing 97.5-100% by volume of pure, concentrated ethanol)