You asked:

Is witch hazel the same thing as rubbing alcohol?

No
rubbing alcohol
rubbing alcohol

rubbing alcohol, USP / B.P., the liquid prepared and used primarily for topical application

witch hazel

witch hazel, an astringent produced from the leaves and bark of the North American Witch-hazel shrub, which grows naturally from Nova Scotia west to Ontario, Canada, and south to Florida and Texas in the United States

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