You asked:

Is Prince Charles older than Pierce Brosnan?

Yes
Pierce Brosnan
Pierce Brosnan

Pierce Brendan Brosnan, OBE (born 16 May 1953), the Irish actor, film producer and environmentalist, who holds both Irish and American citizenship

Prince Charles
Prince Charles

The Prince Charles, Prince of Wales, the eldest child of Queen Elizabeth II and Prince Philip, Duke of Edinburgh, making him heir apparent, equally and separately, to the thrones of 16 independent states

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