You asked:

Is Nizhny Novgorod more populous than Nizhnekamsk?

Yes
Nizhnekamsk
Nizhnekamsk

Nizhnekamsk, the city in the Republic of Tatarstan, Russia, located to the south of the Kama River between the cities of Naberezhnye Chelny and Chistopol

Nizhny Novgorod
Nizhny Novgorod

Nizhny Novgorod, colloquially shortened to Nizhny, is, with the population of 1,250,615, the fifth largest city in Russia

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