You asked:

Is Cayenne pepper the same as Chili powder?

No
Cayenne pepper
Cayenne pepper

cayenne pepper—also known as the Guinea spice, cow-horn pepper, aleva, bird pepper, or, especially in its powdered form, red pepper—is a red, hot chili pepper used to flavour dishes and for medicinal purposes

Chili powder
Chili powder

Chili powder, a generic name for any powdered spice mix composed chiefly of chili peppers, most commonly either red peppers or cayenne peppers, which are both of the species Capsicum annuum

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Other ways this question is asked:

  • is [substance from: [cayenne pepper]] the same as [chili powder]